研究主題

觸媒及反應工程
我的研究領域是觸媒，反應工程，及程序&產品開發。過去數年已研究過以下主要事項：1.含金屬 ZSM-5 及 AlPO₄-5 微孔洞分子篩之合成及鑑定；2.乙烷氧化脫氫反應；3.由丙烷合成苯類產物；4.改善合成 PET 之 Sb₂O₃ 觸媒系統；5.研發廢 PET 之分解程序；6.由選擇性催化燃燒氫氣以改善異丁烯製程。近年研究內容則包括: 1. 研發奈米金材料，應用該材料於低溫下轉化或催化燃燒一氧化碳氣體，並應用該材料於防毒口罩或燃料電池系統。2. 研發及製造多重能隙高效率光電池，及應用該光電池系統於發電，或於光催化水分解程序中製造氫氣（乾淨能源）。3. 研發中孔型二氧化矽材料以製備低介電薄膜及抗反射膜，並應用相關材料於積體電路、光電池及電視螢幕。

最新研究

1. Preparation of Molecular Sieve Type Silica for the Applications in Low-k Films (1/2), 製備分子篩孔洞型二氧化矽膠體液及應用於製備低介電薄膜 (1/2), NSC 97-2221-E-002-089-MY2 , NT$ 1,176,000, 8/1/2008 – 7/31/2009.

榮譽獎項

1. Guest Editor of Catalysis Today, for special issue “Catalysis for New Energy Resources and Environmental Protection”, Volume 97, Issues 2-3, 27 October 2004.  ISSN 0920-5861

2. Catalyst Committee of international conference, GOLD 2006, Limerick, Ireland, September 3 to 6, 2006.

3. Organization Committee of 2008 Taiwan/Korea/Japan ChE Conference and 55th TwIChE Annual Conference, Taipei, Taiwan, November 20 to 22, 2008.

代表著作 所有著作

1. J.-N. Lin and B.-Z. Wan, “Reaction Kinetics of Propane Catalytic Combustion on Cr/γ-Al2O3, Co/Cr/γ-Al2O3, and Au/Cr/γ-Al2O3,” Journal of the Chinese Institute of Chemical Engineers, 35/2, 149-159 (2004). (SCI, EI)

 

2. J.-H. Liu, Y.-S. Chi, H.-P. Lin, C.-Y. Mou and B.-Z. Wan, “Design of a High-Performance Catalyst for CO Oxidation: Au Nanoparticles Confined in Mesoporous Aluminosilicate,” Catalysis Today, 93-95, 141-147 (2004). (SCI, EI)

 

3. Y.-W. Tai, J.-S. Chen, C.-C. Yang and B.-Z. Wan, “Preparation of Nano-Gold on K2La2Ti3O10 for Producing Hydrogen from Photo-Catalytic Water Splitting,” Catalysis Today, 97, 95-101 (2004). (SCI, EI)

 

4. W.-Y. Yu, C.-P. Yang, J.-N. Lin, C.-N. kuo and B.-Z. Wan, “Preparation of Au/TiO2 for Catalytic Preferential Oxidation of CO under Hydrogen Rich Atmosphere around Room Temperature,” Chemical Communications, 3, 354-356 (2005). (SCI)

 

5. F.-Y. Wang, B.-Z. Wan and S. Cheng, “Study on Gd3+ and Sm3+ Co-Doped Ceria-Based Electrolyte,” Journal of Solid State Electrochemistry, 9, 168-173 (2005). (SCI, EI)

 

6. C.-Y. Ting, H.-S. Sheu and B.-Z. Wan, “Porosity Analysis of Spin-on Mesoporous Silica Films,” Studies in Surface Science and Catalysis, 156, 295-302 (2005). (SCI, EI)

 

7. J.-H. Chen, J.-N. Lin, Y.-M. Kang, W.-Y. Yu, C.-N. Kuo and B.-Z. Wan, “Preparation of Nano-gold in Zeolites for CO Oxidation: Effects of Structures and Number of Ion Exchange Sites of Zeolites,” (Invited) Applied Catalysis A: General, 291, 162-169 (2005). (SCI, EI)

 

8. C.-W. Chiang, A.-Q. Wang, B.-Z. Wan, C.-Y. Mou, “High Catalytic Activity for CO Oxidation of Gold Nanoparticles Confined in Acidic Support Al-SBA-15 at Low Temperatures,” Journal of Physical Chemistry B, 109(38), 18042-18047 (2005). (SCI, EI)

 

9. F.-Y. Wang, S. Cheng, C.-H. Chung and B.-Z. Wan, “Y2O3 and MgO Co-doped Ceria Based Electrolytes,” Journal of Solid State Electrochemistry, 10(11), 879-885 (2006). (SCI, EI)

 

10. C.-Y. Ting, H.-S. Sheu, W.-F. Wu and B.-Z. Wan, “Porosity Effects on Properties of Mesoporous Silica Low-k Films Prepared by Using Tetraethylorthosilicate with Different Templates” Journal of The Electrochemical Society, 154(1), G1-G5 (2007). (SCI, EI).This paper has been selected for the December 4, 2006 issue of Virtual Journal of Nanoscale Science & Technology (published by the American Institute of Physics and the American Physical Society).

 

11. J.-T. Luo, W.-F. Wu, H.-C. Wen, B.-Z. Wan, Y.-M. Chang, C.-P. Chou, J.-M. Chen and W.-N. Chen “The Role of Hydrophobic Group on the Surface of Ultra Low Dielectric Constant Porous Silica Film during Thermal Treatment,” Thin Solid Films, 515, 7275-7280 (2007). (SCI, EI)

 

12. C.-N. Kuo, H.-F. Chen, J.-N. Lin and B.-Z. Wan “Nano-Gold Supported on TiO2 Coated Glass-Fiber for Removing Toxic CO gas from air,” Catalysis Today, 122, 270-276 (2007). (SCI, EI)

 

13. W.-Y. Yu, W.-S. Lee, C.-P. Yang and B.-Z. Wan “Low-Temperature Preferential Oxidation of CO in a Hydrogen Rich Stream (PROX) over Au/TiO2: Thermodynamic Study and Effect of Gold-Colloid pH Adjustment Time on Catalytic Activity,” Journal of the Chinese Institute of Chemical Engineers, 38, 151-160 (2007). (SCI, EI)

 

14. W.-S. Lee, B.-Z. Wan C.-N. Kuo, W.-C. Lee and S. Cheng “Maintaining Catalytic Activity of Au/TiO2 during the Storage at Room Temperature,” Catalysis Communications, 8, 1604-1608 (2007). (SCI, EI)

 

15. J.-T. Luo, H.-C. Wen, C.-P. Chou, W.-F. Wu and B.-Z. Wan “Reinforcing Porous Silica with Carbon Nanotubes to Enhance Mechanical Performance,” J. of Composite Materials, 41(8), 979-991 (2007). (SCI, EI)

 

16. F.-Y. Wang, S. Cheng, B.-Z. Wan, C.-H. Chung and M.-J. Chen “A Novel Method for Preparing Highly Porous Gadolinia-Doped-Ceria Ceramics,” Ceramic Int., 34, 1989-1992 (2008). (SCI, EI)

 

17. F.-Y. Wang, S. Cheng, B.-Z. Wan “Porous Ag-CGO Cermets as Anode Materials for ITSOFC Using CO Fuel,” Catalysis Communications, 9, 1519-1599 (2008). (SCI, EI)

 

18. C.-T. Tsai, H.-Y. Lu, C.-Y. Ting, W.-F. Wu, and B.-Z. Wan “Increasing Mechanical Strength of Mesoporous Silica Thin Films by Addition of Tetrapropylammonium Hydroxide and Refluxing Processes,” Thin Solid Films, 517, 2039-2043 (2009). (SCI,EI)

 

19. T.-R. Lin, B.-Z. Wan, H.-P. Lin and C.-Y. Mou “Desulfurization of Vacuum Gasoil by MCM-41 Supported Molybdenum-Nickel Catalysts,” I&EC Research, accepted. (SCI,EI)

 

.

 

 

Patents

 

1. 陳忠吾,萬本儒,陳劉旺,”一種增加PET反應速率的方法”,中華民國發明專利第71477號, 專利期間 1995/04/21-2013/12/02.

 

2. 萬本儒,高志宇,林建作,”低碳烷類的轉化反應”,中華民國發明專利第71752號, 專利期間 1995/06/11-2013/08/02.

 

3. B.-Z. Wan and Y.-M. Kang, “Preparation of Supported Gold Catalysts for Carbon Monoxide Oxidation,” US Patent 5,550,093, 專利期間1996/08/27-2015/06/14.

 

4. 高志宇,萬本儒,”鎵/HZSM-5觸媒系統製備方法”,中華民國發明專利第84386號, 專利期間 1997/01/21-2014/05/02.

 

5. 萬本儒,蕭志揚,康義明,”製備催化一氧化碳氧化反應之金鐵鋁矽觸媒的方法”,中華民國發明專利第97979號, 專利期間 1998/07/11-2014/09/14.

 

6. 鄭武順,萬本儒,高志宇,”利用觸媒於聚對苯二甲酸乙二酯分解製程的方法”,中華民國發明專利第142348號, 專利期間 2001/08/01-2017/04/08.

 

7. 萬本儒,林立千,楊國峰,”一種增加PET合成之聚縮合反應速率的方法”,中華民國發明專利第160524號, 專利期間 2002/08/01-2018/10/13.

 

8. 萬本儒,陳皇甫,林俊男,郭建男,游文岳,”去除一氧化碳之含奈米金纖維製備方法”,中華民國發明專利第I239856號, 專利期間 2005/09/21-2022/11/19.

 

9. 萬本儒,丁致遠,歐陽德發,”具有低介電常數之多孔性氧化矽薄膜的製造方法”,中華民國發明專利第I243149號, 專利期間 2005/11/11-2021/03/29.

 

10. 丁致遠,蔡承宗,萬本儒,”增加孔洞型二氧化矽薄膜材料機械強度之方法”,中華民國發明專利第I243415號, 專利期間 2005/11/11-2024/12/14.

 

 

Technology Transfer

 

1. “去除一氧化碳之含奈米金防毒面罩材料開發研究”, 耀文企業有限公司, 91/8/1~96/8/1, NT$ 50000.

 

2. “含奈米金纖維改進研究”, 耀文企業有限公司, 93/8/1~98/8/1, NT$ 50000.